Archived publication
This publication is no longer current or has been superseded.
This appendix contains information on the manufacturing industries that were researched in the What’s in your waste? report. The industries include electroplating and fertiliser manufacturing
| Process | Waste stream | Type of waste | Waste constituent |
Current management
practices (best management practice in bold) |
New Zealand Waste List
entry (* waste should be treated as hazardous) |
|---|---|---|---|---|---|
| Alkaline cleaning | Solution builders | Liquid | Alkali carbonates, alkali hydroxides |
Heavy metal treatment, pacified, disposed to sewer if in
accordance with trade waste consent Heavy metal treatment, pacified, solidified, landfilled |
11 01 07* Pickling bases |
| Solution additives | Liquid | Organic and inorganic additives | At the time of disposal there are part of the total bath make-up and treated as above. All goes to waste collector. |
11 01 99 Wastes from chemical surface treatment ... Wastes not otherwise specified |
|
| Surfactants | Liquid | Kerylbenzene sulphonate | As above | ||
| Acid cleaning | Waste acid | Liquid | Sulphuric acid, hydrochloric acid, hydrofluoric acid, nitric acid | Disposal/heavy metal treatment by waste collector |
11 01 05* Pickling acids |
| Anodising | Anodising waste | Liquid | Chromic acid, sulphuric acid, boric-sulphuric acid |
Heavy metal treatment, pacified, disposed to sewer if in
accordance with trade waste consent Heavy metal treatment, pacified, solidified, landfilled |
11 01 06* Acids not otherwise specified |
| Sealants | Liquid | Chromic acid, nickel acetate, nickel-cobalt acetate |
11 01 98* Wastes from chemical surface treatment ... Other wastes containing hazardous substances |
||
| Chemical conversion coating | Chromating wastes | Liquid | Hexavalent chromium |
Hexavalent chromium reduced to trivalent chromium Wastewater pre-treated on site |
11 01 98* Wastes from chemical surface treatment ... Other wastes containing hazardous substances |
| Sludge | Base metals, chrome | Treated for heavy metals, landfilled |
11 01 09* Sludges and filter cakes containing hazardous substances |
||
| Phosphating wastes | Sludge/ spent solution | Phosphate salts, phosphoric acid, base metals, other reagents | Treated for heavy metals, landfilled |
11 01 08* Phosphate sludges |
|
| Passivating wastes | Liquid | Nitric acid, sodium dichromate | Treated for heavy metals, landfilled |
11 01 06* Acids not otherwise specified |
|
| Electroplating | Wastewater | Liquid/ spent solutions | Sodium cyanide, potassium cyanide | Waste is collected and treated off-site |
11 01 98* Wastes from chemical surface treatment ... Other wastes containing hazardous substances |
| Sludge | Treated for heavy metals, landfilled |
11 01 09* Sludges and filter cakes containing hazardous substances |
|||
| Electroless plating | Plating solution | Liquid | Buffer, complexing agent, metal salts, reducer, cyanide compounds | Treated for heavy metals, landfilled |
11 01 98* Wastes from chemical surface treatment ... Other wastes containing hazardous substances |
| Sludges | Treated for heavy metals, landfilled |
11 01 09* Sludges and filter cakes containing hazardous substances |
|||
| Painting/ powder coating | Waste paint | Liquid | Acrylic, enamel, isocyanate based paints, basecoats | Solidified, landfilled |
08 01 11* Waste paint and varnish containing organic solvents or other hazardous substances |
| Waste powders | Solid |
Landfilled Recovered on site |
|||
| Etching | Etching solutions | Liquid | Ammonium persulphate, chromic acid | Waste is collected and treated off-site |
11 01 98* Wastes from chemical surface treatment ... Other wastes containing hazardous substances |
ChemWaste Industries Ltd, 10 Barton Street, Woolston
Professional Plating Services, 41 Coleridge Street, Christchurch
| Process | Waste stream | Type of waste | Waste constituent |
Current management
practices (best management practice in bold) |
New Zealand Waste List
entry (* waste should be treated as hazardous) |
|---|---|---|---|---|---|
| Primary production | |||||
| Forming | Cooling water | Liquid | Biocides, particulate, polycyclic aromatic hydrocarbons (PAH) | Recycled, but has some bleed-off to storm water |
10 03 28 Wastes from cooling-water treatment other than those mentioned in 10 03 27* |
| Anode scraps | Solid | Carbon, PAH | Recycled |
10 03 02 Anode scraps |
|
| Tarry wastes | Solid | Carbon, PAH | Off-site recycling |
10 03 17* Tar containing wastes from anode manufacture |
|
| Baking | Carbon dusts | Solid | Carbon | Recycled |
10 03 18 Carbon-containing wastes from anode manufacture other than those mentioned in 10 03 17* |
| Waste furnace lining | Solid | Used refractory | Off-site recycling |
16 11 04 Other linings and refractories from metallurgical processes other than those mentioned in 16 11 03* |
|
| Anode scraps | Solid | Carbon | Recycled |
10 03 02 Anode scraps |
|
| Rodding | Cooling water | Liquid | Biocides | Recycled with some bleed-off to stormwater |
10 03 28 Wastes from cooling-water treatment other than those mentioned in 10 03 27* 16 10 01* Aqueous liquid wastes containing hazardous substances |
| Carbon dust, anode butts | Solid | Carbon | Recycled |
10 03 18 Carbon-containing wastes from anode manufacture other than those mentioned in 10 03 17* |
|
| Bath wastes | Solid | Fluorides | Recycled |
10 03 99 Wastes from aluminium thermal metallurgy Wastes not otherwise specified |
|
| Reduction | Spent cell lining | Solid | Carbon, fluorides | Stored |
16 11 01* Carbon-based linings and refractories from metallurgical processes containing hazardous substances |
| Casting | Cooling water | Liquid | Biocides |
Intercepted, oil separated, discharge of water to stormwater
if in accordance with resource consent Oil recycled off-site |
10 03 28 Wastes from cooling-water treatment other than those mentioned in 10 03 27* 16 10 01* Aqueous liquid wastes containing hazardous substances |
| Used oil | Liquid | Oil |
10 03 27* Wastes from cooling-water treatment containing oil |
||
| Processing fines | Solid | Aluminium, aluminium oxide, fluorides | Landfilled |
10 03 04* Primary production slags |
|
| Non-cast aluminium | Solid | Aluminium powder, fluorides | Off-site recycling |
10 03 04* Primary production slags |
|
| Waste furnace lining | Solid | Used refractory | Landfilled |
16 11 04 Other linings and refractories from metallurgical processes other than those mentioned in 16 11 03* |
|
| General operations | Non-ferrous metal waste | Solid | Primarily iron | Off-site recycling |
10 03 99 Wastes from aluminium thermal metallurgy Wastes not otherwise specified |
| Baghouse bags | Solid | Polyester | Landfilled |
10 03 99 Wastes from aluminium thermal metallurgy Wastes not otherwise specified |
|
| Used oil | Liquid | Oil | Off-site recycling |
13 05 06* Oil from oil/water separators |
|
| Oily water | Liquid | Oil | Recycled |
16 10 01* Aqueous liquid wastes containing hazardous substances |
|
| Paper and cardboard | Solid | Paper, cardboard |
Paper disposed of to off-site landfill Cardboard recycled off-site |
15 01 01 Paper and cardboard packaging |
|
| Insulation material | Solid | Asbestos | Contained and disposed of to landfill |
17 06 01* Insulation materials containing asbestos |
|
| Secondary production | |||||
| Furnace heating | Aluminium dross | Solid | Aluminium nitride, aluminium carbide, aluminium powder, aluminium oxide |
Treated through off-site ball milling and sieving Resources recovered and disposed of to controlled landfill |
10 03 09* Black dross from secondary production 10 03 15* Skimmings that are flammable or emit, upon contact with water, flammable gases in hazardous quantities |
| Salt cake | Solid | Sodium chloride, potassium chloride, aluminium oxide, aluminium | Disposed of to a controlled landfill |
10 03 08* Salt slags from secondary production |
|
| Bag House dust | Solid | Sodium chloride, potassium chloride, zinc, lead, copper, calcium carbonate, aluminium oxide | Stabilised and landfilled |
10 03 21* Other particulates and dust (including ball-mill dust) containing hazardous substances |
|
| Cooling | Water | Liquid | Biocides | Recycled and discharged to sewer if in accordance with a trade waste consent |
16 10 01* Aqueous liquid wastes containing hazardous substances. |
| Casting | Oily water | Liquid | Hydrocarbons | Treated through interceptors and discharged to sewer if in accordance with a trade waste consent |
10 03 27* Wastes from cooling-water treatment containing oil. |
| Use of wash water | Waste oil | Liquid | Hydraulic and lubricating oils | Recovered and collected as part of the Used Oil Recovery Programme |
13 02 04*–13 02 08* Waste engine, gear, and lubricating oils 13 01 01*–13 01 13* Waste hydraulic oils |
| Process | Waste stream | Type of waste | Waste constituent |
Current management
practices (best management practice in bold) |
New Zealand Waste List
entry (* waste should be treated as hazardous) |
|---|---|---|---|---|---|
| Skin pass | Waste drums | Solid | Steel drums |
Drums washed and recycled Wash water treated as contact water |
15 01 04 Metallic packaging |
| Roll shop operations | Kerosene | Liquid | Petroleum based hydrocarbons | Collected and combusted on-site |
12 01 07* Mineral-based machining oils free of halogens (except emulsions and solutions) |
| Used grinding wheels | Solid | Used grinding wheels | Landfilled |
12 01 21 Spent grinding bodies and grinding materials other than those mentioned in 12 01 20* |
|
| Waste oil | Liquid | Petroleum based hydrocarbons | Collected and recycled |
12 01 07* Mineral-based machining oils free of halogens (except emulsions and solutions) |
|
| Grindings | Solid | Scrap steel, silicon, oil | Landfilled |
12 01 02 Ferrous metal dust and particles |
|
| Roll packaging | Solid | Corrugated cardboard, strapping, timber, plastic | Landfilled |
15 01 01–15 01 03 Paper, cardboard, plastic and wooden packaging |
|
| Turnings | Solid | Steel | Landfilled |
12 01 01 Ferrous metal filings and turnings |
|
| Grinder coolants | Liquid | Water oil emulsion |
Collected by an off-site contactor Discharged to sewer if meets trade waste consent |
12 01 09* Machining emulsions and solutions free of halogens |
|
| Shot blaster grit | Solid | Grit | Landfilled |
12 01 17 Waste blasting material other than those mentioned in 12 01 16 |
|
| Rolling mill utilities | Temper fluid | Liquid | Temper fluid, water | Evaporated on drying beds |
16 10 01* Aqueous liquid wastes containing hazardous substances |
| Tallow based waste oil | Liquid | Waste oil | Collected by off-site contractor, used for boiler fuel |
12 01 10* Readily biodegradable machining oil |
|
| DAF thickener | Sludge | Dried on on-site drying beds and landfilled |
19 08 14 Sludges from other treatment of industrial wastewater other than those mentioned in 19 08 13 |
||
| Mill scale | Solid | Scale | Vanadium is recovered and mill scales recycled |
10 02 10 Mill scales |
|
| Mineral oils | Liquid | Oil | Collected and disposed of through the Used Oil Recovery Programme |
12 01 07* Mineral-based machining oils free of halogens (except emulsions and solutions) |
|
| Hot rolling | Primary scale | Solid | Steel | Recycled |
10 02 10 Mill scales |
| Furnace entry scale | Solid | Iron, dust, sand, pebbles | Landfilled |
12 01 02 Ferrous metal dust and particles |
|
| Reheat furnace scale | Solid | Steel |
Water blasted and recycled Landfilled |
10 02 10 Mill scales |
|
| Hot mill cellar oily waste | Liquid | Oil and water | Collected by waste contractor and discharged to sewer if in accordance with trade waste consent |
12 01 09* Machining emulsions and solutions free of halogens |
|
| Cold rolling | Ferrous oxide | Solid | Ferrous oxide | Landfilled |
12 01 99 Wastes from shaping and physical and mechanical surface treatment of metals and plastics Wastes not otherwise specified |
| Pipe fabrication | Pickling waste | Liquid | Hydrochloric acid | Neutralised on site and discharged to sewer if in accordance with trade waste consent |
06 01 02* Hydrochloric acid |
| Emulsion and mill scale | Liquid | Oily emulsion, mill scale | Dried on on-site drying beds, then disposed to landfill |
12 01 09* Machining emulsions and solutions free of halogens |
|
| Sodium dichromate waste | Liquid | Water, sodium dichromate waste |
Off-site reduction and precipitation Discharged to sewer if in accordance with trade waste consent |
16 09 02* Chromates, e.g. potassium chromate, potassium or sodium dichromate |
|
| Bottom dross | Solid | Iron | Collected for metal recovery by off-site contractor |
12 01 99 Wastes from shaping and physical and mechanical surface treatment of metals and plastics Wastes not otherwise specified |
|
| Zinc dust | Solid | Zinc | Collected for metal recovery by off-site contractor | New code – to be confirmed | |
| Zinc sludge | Sludge | Zinc | Treated by on-site centrifugation, dried and landfilled |
12 01 14* Machining sludges containing hazardous substances |
|
| General operations | Scrap steel, scrap steel rods, steel sheet scrap, cobbles and abort materials, steel crops | Solid | Steel | Recycled |
10 02 99 Wastes from iron and steel industry Wastes not otherwise specified |
| Process | Waste stream | Type of waste | Waste constituent |
Current management
practices (best management practice in bold) |
New Zealand Waste List
entry (* waste should be treated as hazardous) |
|---|---|---|---|---|---|
| Pressure treatment | Packaging waste | Solid |
Drums, paper bags, plastic (except PVC). May contain copper, chromium, arsenic, boron, tri-n-butyl tin oxide, tri-n-butyl tin naphthenate, copper naphthenate, copper-8-hydroxyquinolate, insecticides, solvents |
Drums washed and recycled and wash water treated as contact
water Paper and plastic incinerated in accordance with landfill acceptance criteria |
15 01 09* Packaging containing residues of or contaminated by hazardous substances |
| Sludge | Sludge | Copper, chromium, arsenic, boron | Dewatered, stabilised and landfilled | New code – to be confirmed | |
| Tri-n-butyl tin oxide, tri-n-butyl tin naphthenate, copper naphthenate, copper-8-hydroxyquinolate, insecticides, solvents | Chemically oxidised, stabilised and solidified and landfilled | ||||
| Offcut waste | Solid | Offcuts and sawdust, containing copper, chromium, arsenic, boron, tri-n-butyl tin oxide, tri-n-butyl tin naphthenate, copper naphthenate, copper-8-hydroxyquinolate, insecticides, solvents | Incinerated (see footnote 1) or landfilled if in accordance with landfill acceptance criteria |
03 01 04* Sawdust, shavings, cuttings, wood, particle board and veneer containing hazardous substances |
|
| Contact water | Liquid | Copper, chromium, arsenic | pH adjustment, precipitated and disposed of to sewer if in accordance with trade waste consent |
16 10 01* Aqueous wastes destined for off-site treatment Aqueous liquid wastes containing hazardous substances |
|
| Boron | pH adjustment, crystallisation, filtration and disposal to sewer if in accordance with trade waste consent | ||||
| Tri-n-butyl tin oxide, tri-n-butyl tin naphthenate, copper naphthenate, copper-8- hydroxyquinolate, insecticides, solvents | Chemical oxidation stabilisation, and solidification, then disposed of to landfill | ||||
| Vapour treatment | Packaging waste | Solid |
Drums, paper bags, plastic (except PVC) Contain boron |
Drums washed and recycled wash water treated as contact
water Paper and plastic incinerated in accordance with landfill acceptance criteria |
15 01 09* Packaging containing residues of or contaminated by hazardous substances |
| Sludge | Sludge | Boron | Dewatered, stabilised and landfilled | New code – to be confirmed | |
| Offcut waste | Solid | Offcuts and sawdust, containing boron | Incinerated or landfilled if in accordance with landfill acceptance criteria |
03 01 04* Sawdust, shavings, cuttings, wood, particle board and veneer containing hazardous substances |
|
| Contact water | Liquid | Boron | pH adjustment, precipitated and disposed of to sewer if in accordance with trade waste consent |
16 10 01* Aqueous wastes destined for off-site treatment Aqueous liquid wastes containing hazardous substances |
|
| Diffusion treatment | Packaging waste | Solid |
Drums, paper bags, plastic (except PVC). Contains tri-n-butyl tin oxide, tri-n-butyl tin naphthenate, copper naphthenate, copper-8- hydroxyquinolate, insecticides, solvents |
Drums washed and recycled, wash water treated as contact
water Paper and plastic incinerated in accordance with landfill acceptance criteria |
15 01 09* Packaging containing residues of or contaminated by hazardous substances |
| Sludge | Sludge | Tri-n-butyl tin oxide, tri-n-butyl tin naphthenate, copper naphthenate, copper-8- hydroxyquinolate, insecticides, solvents | Dewatered, stabilised and landfilled | New code – to be confirmed | |
| Offcut waste | Solid | Offcuts and sawdust, containing tri-n-butyl tin oxide, tri-n-butyl tin naphthenate, copper naphthenate, copper-8- hydroxyquinolate, insecticides, solvents | Incinerated or landfilled if meets landfill acceptance criteria |
03 01 04* Sawdust, shavings, cuttings, wood, particle board and veneer containing hazardous substances |
|
| Contact water | Liquid | Tri-n-butyl tin oxide, tri-n-butyl tin naphthenate, copper naphthenate, copper-8- hydroxyquinolate, insecticides, solvents | pH adjustment, precipitated and disposed of to sewer if in accordance with trade waste consent |
16 10 01* Aqueous wastes destined for off-site treatment Aqueous liquid wastes containing hazardous substances |
| Process | Waste stream | Type of waste | Waste constituent |
Current management
practices (best management practice in bold) |
New Zealand Waste List
entry (* waste should be treated as hazardous) |
|---|---|---|---|---|---|
| Material transfer and storage | Leaked and spilt raw materials | Solid/ liquid | Hydrocarbons | Remediation by contractor and landfilled |
05 01 05* Oil spills 19 13 01* Solid wastes from soil remediation containing hazardous substances 19 13 07* Aqueous liquid wastes and aqueous concentrates from groundwater remediation containing hazardous substances |
| Solid | Cleaning cloths |
15 02 02* Absorbents ... wiping cloths ... contaminated by hazardous substances |
|||
| Storage tank sludges | Sludge | Hydrocarbons | Stabilised and landfilled |
05 01 03* Tank bottom sludges |
|
| Cracking | Waste coke | Solid | Carbon | Collected, recovered and recycled |
05 01 99 Wastes from petroleum refining Wastes not otherwise specified |
| Spent catalysts | Solid | Spent catalysts |
16 08 04 Spent fluid catalytic cracking catalysts |
||
| Reforming | Spent catalysts | Solid | Platinum, rhenium | Collected, recovered and recycled |
16 08 01 Spent catalysts containing gold, silver, rhenium ... |
| Waste coke | Solid | Carbon |
05 01 99 Wastes from petroleum refining Wastes not otherwise specified |
||
| Sulphur removal | Spent catalyst | Solid | Molybdenum, cobalt, nickel, zinc, copper | Collected, recovered and recycled |
16 08 02* Spent catalysts containing hazardous transition metals or transition metal compounds |
| ADIP solution | Liquid | Di-isopropylmaine, water |
05 01 16* Sulphur-containing wastes from petroleum desulphurisation |
||
| Cooling towers | Cooling water | Liquid | Water, biocides | Recycled, overflow discharge to stormwater |
05 01 14* Wastes from cooling columns |
| Hydrogen manufacture | Sulfinol absorption solution | Liquid | Di-isopropylamine, sulfolane, water | Recycled in process | New code – to be confirmed |
| General operations | Refractory waste | Solid | Used refractory | Landfilled |
16 11 05* Linings and refractories from non-metallurgical processes containing hazardous substances 16 11 16 Linings and refractories from non-metallurgical processes other than those specified in 16 11 05* |
| Insulation material | Solid | Includes asbestos | Landfilled |
Insulation materials other than those mentioned in 17 06
01* and 17 06 03* 17 06 01* Insulation materials containing asbestos |
|
| Maintenance wastes | Solid/ sludge | Hydrocarbon | Landfilled |
05 01 06* Oily sludges from maintenance operations of the plant or equipment |
|
| Effluent treatment sludge | Sludge | Biomass | Landfilled |
05 01 09* Sludges from on-site effluent treatment containing hazardous substances |
| Process | Waste stream | Type of waste | Waste constituent |
Current management
practices (best management practice in bold) |
New Zealand Waste List
entry (* waste should be treated as hazardous) |
|---|---|---|---|---|---|
| Void tower scrubber operations | Scrubber effluent | Liquid | Fluoride and some acid gas in solution (SO2 and SiF4), sea water | Recycled for acid dilution and granulation |
06 01 01 Sulphurous acid 06 01 06 Other acids |
| Polishing void scrubber and hygiene vent |
Discharged to harbour via settling pond together with
remaining sea water from acid plant cooling and any
stormwater Discharged to harbour together with other site effluent (primarily boiling and cooling tower blowdown) |
||||
| Three stage venturi scrubber operations | Scrubber effluent | Liquid | Fluoride and some acid gas in solution (SO2 and SiF4), sea water |
Recycled for acid dilution and granulation Some sold for water supply fluoridation |
06 01 01 Sulphurous acid 06 01 06 Other acids |
| Venturi scrubber cleaning and spillage | Discharged to a stream after neutralisation with lime, together with other effluent and any stormwater in compliance with a resource consent |
By looking at the ‘big picture’, businesses can assess areas in their operation where they can minimise or manage waste. This is called Cleaner Production and means:
The aim of Cleaner Production is to reduce the adverse impacts of production and service activities on the environment. Implementing Cleaner Production practices has many benefits. These include consistent and significant reductions in energy and water consumption, waste disposal, emissions and associated costs including trade waste discharge costs and landfill charges. Many of these improvements result from simple "good housekeeping" changes or implementing ideas from workers themselves. Often, once Cleaner Production has been achieved in one area of the business, it becomes easier to see other areas in which it can be achieved.
A number of New Zealand companies have been involved in a series of projects that demonstrate the benefits of Cleaner Production. These businesses have received considerable support and assistance from BusinessCare and Christchurch City Council’s Target Zero team. Some of the examples of Cleaner Production initiatives are included in this section. As the New Zealand case studies do not cover the entire range of businesses researched for this report, some of the included examples are from Australia. Where this is the case, it is important to remember that the costs and savings identified are in $AUS.
This section is intended to show what can be done by businesses and does not in any way suggest in any way that this is what the Ministry for the Environment thinks should be done. The businesses shown in the case studies may not carry out the exact processes outlined in the tables above, however they are in the same type of industry. A list of websites containing further information on Cleaner Production case studies is shown in the Bibliography.
Electroplating business employing 23 staff and specialising in bright zinc plating, gold passivating and related finishes.
For the full article see: www.businesscare.org.nz/material/caseStudies/c2764_4.html
A small metal plating and powder coating firm.
For the full article see: www.ea.gov.au/industry/corporate/eecp/case-studies/protect.html
Manufacturers of phosphate fertilisers for New Zealand’s agricultural industry.
For the full article see: www.businesscare.org.nz/material/caseStudies/c253_1.html
Produces 150,000 tonnes of aluminium per annum.
For the full article see: www.ea.gov.au/industry/corporate/eecp/case-studies/comalco.html
The ICI Olefines plant at Botany, New South Wales, produces hydrocarbons that are primarily used in the manufacture of plastics. The production capacity of the plant is 250,000 tonnes of ethylene per annum.
For the full article see: http://www.ea.gov.au/industry/corporate/eecp/case-studies/ici.html