The general methodology provided in the Timber Treatment Guidelines (Ministry for the Environment and Ministry of Health 1997) and the Gasworks Guidelines (Ministry for the Environment 1997) was used to derive the indicative soil guideline values provided in section 5, which are consistent with existing New Zealand guidelines.
In contrast to previous guidelines, this guideline explicitly includes lifestyle-block land use as a typical New Zealand land use, which assumes that 50 percent of the produce consumed by residents is grown on-site (consumption of meat, milk and eggs of animals raised on-site is excluded). Previously this land use has been a subset of residential land use. The standard residential land-use category considered here assumes that 10 percent of the produce consumed by residents is grown on-site, while the remaining categories do not consider consumption of produce grown on-site.
The following five land-use categories were adopted.
The exposure scenarios considered are largely based on those provided in the Gasworks Guidelines, while the parameter values used are based on those contained in both guidelines. They are consistent with those used internationally and are also generally considered to be representative of New Zealand for the purpose of deriving generic values. However, different parameters have been used for the dermal exposure and produce consumption pathways.
Table A.3 provides a summary of the exposure parameters used for each scenario. The equations used to derive soil guideline values are provided in Cavanagh and Proffitt (2005).
Table A.3: Summary of the exposure parameters for each land-use scenario
|
Pathway |
Lifestyle block (50% produce consumption) |
Residential (10% produce consumption) |
High-density residential |
Parkland/ recreational |
Commercial/ |
|---|---|---|---|---|---|
|
Exposure frequency (days/year) |
350 |
350 |
350 |
350 |
240 |
|
Exposure duration - child (years) |
6 |
6 |
6 |
6 |
- [Not applicable] |
|
Exposure duration - adult (years) |
24 |
24 |
24 |
24 |
20 |
|
Averaging time - non-threshold(years) |
70 |
70 |
70 |
70 |
70 |
| Body weight (kg): | |||||
|
15 | 15 | 15 | 15 | - [Not applicable] |
|
70 |
70 |
70 |
70 |
70 |
|
Ingestion pathway |
|||||
|
Soil ingestion rate (mg/day): |
|||||
|
100 | 100 | 100 [Soil ingestion rates are different from the Gasworks Guidelines, to achieve consistency with the arsenic guideline values.] | 50 | |
|
25 | 25 | 25 [Soil ingestion rates are different from the Gasworks Guidelines, to achieve consistency with the arsenic guideline values.] | 10 | 25 |
|
Produce (kg/day): [Wet weight (dry weight).] |
|
|
|||
|
0.077 (0.011) | 0.077 (0.011) | - [Not applicable] | - [Not applicable] | - [Not applicable] |
|
0.254 (0.034) | 0.254 (0.034) | |||
| Portion home-grown (%) | 50 | 10 | |||
|
Inhalation pathway |
|||||
|
Exposure duration (hours/day) |
24 |
24 |
24 |
5 |
8 |
|
Particulate concentration (μg/m3) |
50 |
50 |
50 |
50 |
142 |
|
Inhalation rate (m3/day): |
|
|
|
||
|
7.6 | 7.6 | 7.6 | 7.6 | - [Not applicable] |
|
25 | 25 | 25 | 25 | 1.3 [m3/hour.] |
|
Dermal pathway |
|||||
|
Exposure duration (hours/day) |
12 |
12 |
12 |
8 |
8 |
|
Exposed skin surface area (cm2): |
|
|
|
|
|
|
2,625 | 2,625 | 2,625 | 2,625 | - [Not applicable] |
|
4,700 | 4,700 | 4,700 | 4,700 | 4,700 |
|
Soil adherence factor (mg/cm2): |
|||||
|
0.2 | 0.2 | 0.2 | 0.2 | 0.2 |
|
0.07 | 0.07 | 0.07 | 0.07 | |
Contaminant-specific parameters used to derive soil guideline values in the current report are summarised in Table A.4, and a brief discussion is provided below.
Table A.4: Contaminant-specific parameters used to derive soil guideline values
|
Pathway |
DDT |
Dieldrin |
Lindane |
|---|---|---|---|
|
Tolerable daily intake (mg/kg-bw/day) |
0.0005 |
0.0001 |
0.005 |
|
Background exposure (mg/kg-bw/day) [Subtracted from the TDI.] |
0.000041 |
− |
− |
|
Dermal absorption factor |
0.01 |
0.1 |
0.04 |
|
Plant uptake factor |
0.136 |
0.41 |
0.41 |
The toxicological intake values provided by the World Health Organisation were generally used in the current report to provide consistency with toxicological intake values adopted by other government agencies such as the Ministry of Health, Environmental Risk Management Authority and New Zealand Food Safety Authority. With the exception of DDT, the intake values are consistent with those values used in the Drinking-water Standards for New Zealand 2005 (Ministry of Health 2005). Table A.5 provides a summary of the soil guideline values derived for individual pathways, and the final combined value.
Table A.5: Summary of soil guideline values (mg/kg) for individual pathways
|
Contaminant |
Scenario |
Soil ingestion |
Dermal absorption |
Produce ingestion |
Combined [The combined value is calculated by taking the inverse of the sum of the inverse value of each pathway.] |
|---|---|---|---|---|---|
|
∑DDTs |
Rural/lifestyle |
72 |
2,735 |
9.6 |
8.4 |
|
Standard residential |
72 |
2,735 |
48 |
28 |
|
|
High-density urban residential |
72 |
2,735 |
- |
70 |
|
|
Parks/recreation |
143 |
4,100 |
- |
139 |
|
|
Commercial/industrial |
1,955 |
15,600 |
- |
1,740 |
|
|
Dieldrin |
Rural/lifestyle |
16 |
60 |
0.7 |
0.7 |
|
Standard residential |
16 |
60 |
3.4 |
2.7 |
|
|
High-density urban residential |
16 |
60 |
- |
12 |
|
|
Parks/recreation |
31 |
89 |
- |
23 |
|
|
Commercial/industrial |
425 |
339 |
- |
190 |
|
|
Lindane |
Rural/lifestyle |
782 |
7,450 |
35 |
33 |
|
Standard residential |
782 |
7,450 |
173 |
139 |
|
|
High-density urban residential |
782 |
7,450 |
- |
707 |
|
|
Parks/recreation |
1,560 |
11,200 |
- |
1,370 |
|
|
Commercial/industrial |
> 20,000 |
> 20,000 |
- |
14,180 |
The Ministry for the Environment holds more detailed information on the derivation of the soil guideline values for individual contaminants. This information can be provided on request.
A summary of the existing national and international soil guideline values for the protection of ecological receptors for the sheep-dip contaminants of concern are shown below.
Table A.6: Soil guideline values protective of on-site ecological receptors (mg/kg)
|
Country |
Value name |
Arsenic |
DDT |
Dieldrin |
Lindane |
Source |
|---|---|---|---|---|---|---|
|
New Zealand |
Minimal risk guideline value |
12 |
1.8 |
0.002 |
0.006X |
Cavanagh and O'Halloran 2006 xCavanagh and Booth 2003 |
|
Serious risk guideline value |
22 |
13 |
0.5 |
2.1X |
||
|
Soil limita |
20 |
- |
- |
- |
NZWWA 2003 |
|
|
Waste-screening criteriab |
12, 1.2 |
500 |
8, 0.8 |
- |
Ministry for the Environment 2004b |
|
|
Australia |
EIL |
20 |
- |
- |
- |
NEPC 1999 |
|
Canada |
SQGe − residential |
17 |
0.7 |
- |
- |
CCME 1999 |
|
Commercial/industrial |
26 |
12 |
- |
- |
||
|
USA |
Eco-SSL − plants |
18 |
P |
NA |
- |
US EPA 2005b, c, d |
|
Invertebrates |
NA |
P |
NA |
- |
||
|
Birds |
43 |
P |
0.0069 |
- |
||
|
Mammals |
46 |
P |
0.000032 |
- |
||
|
The Netherlands |
SRCeco |
40 (85c) |
4d |
4e |
- |
Lijzen et al 2001 |
|
IV |
55 |
4d |
4e |
- |
||
|
MPC |
34 |
0.01d |
0.005e |
0.05 |
de Bruijn et al 1999 |
|
|
TV |
29 |
1 × 10-4,d |
5 × 10-4e |
5 × 10-5 |
VROM 2000 |
EIL - ecological investigation level; SQGe - soil quality guideline environmental; Eco-SSL - ecological soil screening level; P - pending; NA − not available, insufficient data for derivation of an Eco-SSL; SRCeco − serious risk concentration ecotox; IV - intervention value; MPC - maximum permissible concentration; TV - target value.
a Allowable limits in soil to which biosolids have been applied.
b Based on protection of off-site receptors.
c Revised value (Lijzen et al 2001).
d Sum of DDT, DDD and DDE.
e Sum of aldrin, dieldrin and endrin.