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Table 8.1: Clean air background concentrations of some atmospheric gases in New Zealand

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Gas

Mean value

Unit

Accuracy +/-

Seasonal range

Comment

Carbon dioxide (CO2)

368

ppm

1.0

1.0

Increasing at 0.4% per year

Carbon monoxide (CO)

0.055

ppm

0.005

0.015

Strong season and space variation

Nitrous oxide (N2O)

0.316

ppm

0.001

0.001

Little space and time variation, increasing at 0.6% per year

Methane (CH4)

1.75

ppm

0.01

0.03

Local sources can bias (eg, strong agricultural sources)

Hydrogen (H2)

0.70

ppm

0.01

0.01

Reasonably constant

Sulphur dioxide (SO2)

0.016

ppb

0.012

0.016

Maximum in summer, practically zero in winter

Nitrogen dioxide (NO2)

< 0.5

ppb

0.5

na

Estimated from urban monitoring

Ozone (O3)

30

ppb

2.0

15

Highest New Zealand levels are often in clean air, and are strongly seasonal. This level is 'natural'.

Particulates (as PM10)

1.0

µg/m3

0.1

1.0

All sea salt

Chlorofluorocarbon (CFC12)

0.50

ppm

0.05

0.01

Recent global increase

Benzene (C6H6)

0.05

ppb

0.01

na

Can be zero in ultra clean air, over 30 ppb in city contaminated air

Other toxics

< dl

 

est.

na

Not measured, but most are below detection limits for the most sensitive equipment

Nitrogen (N2)

780,900

ppm

est.

Not measured routinely in New Zealand

Oxygen (O2)

209,400

ppm

est.

Not measured routinely in New Zealand

Argon (Ar)

9,300

ppm

est.

Not measured routinely in New Zealand

Other inert gases

20

ppm

est.

Not measured routinely in New Zealand